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A comprehensive overview of current developments and applications in biofuels production 

Process Systems Engineering for Biofuels Development brings together the latest and most cutting-edge research on the production of biofuels. As the first book specifically devoted to process systems engineering for the production of biofuels, Process Systems Engineering for Biofuels Development covers theoretical, computational and experimental issues in biofuels process engineering. 

Written for researchers and postgraduate students working on biomass conversion and sustainable process design, as well as industrial practitioners and engineers involved in process design, modeling and optimization, this book is an indispensable guide to the newest developments in areas including: 

  • Enzyme-catalyzed biodiesel production 
  • Process analysis of biodiesel production (including kinetic modeling, simulation and optimization) 
  • The use of ultrasonification in biodiesel production 
  • Thermochemical processes for biomass transformation to biofuels 
  • Production of alternative biofuels 

In addition to the comprehensive overview of the subject of biofuels found in the Introduction of the book, the authors of various chapters have provided extensive discussions of the production and separation of biofuels via novel applications and techniques. 

Table of Contents

  1. Cover
  2. Wiley Series in Renewable Resources
  3. List of Contributors
  4. Series Preface
  5. Preface
  6. 1 Introduction
    1. 1.1 Importance of Biofuels and Overview of their Production
    2. 1.2 Significance of Process Systems Engineering for Biofuels Production
    3. 1.3 Overview of this Book
    4. References
  7. 2 Waste Biomass Suitable as Feedstock for Biofuels Production
    1. 2.1 Introduction
    2. 2.2 Kinds of Feedstock
    3. 2.3 Conclusions
    4. Acknowledgment
    5. References
  8. 3 Multiscale Analysis for the Exploitation of Bioresources: From Reactor Design to Supply Chain Analysis
    1. 3.1 Introduction
    2. 3.2 Unit Level
    3. 3.3 Process Synthesis
    4. 3.4 The Product Design Problem
    5. 3.5 Supply Chain Level
    6. 3.6 Multiscale Links and Considerations
    7. Acknowledgment
    8. Nomenclature
    9. References
  9. 4 Challenges in the Modeling of Thermodynamic Properties and Phase Equilibrium Calculations for Biofuels Process Design
    1. 4.1 Introduction
    2. 4.2 Thermodynamic Modeling Framework: Elements, Structure, and Organization
    3. 4.3 Thermodynamics of Biofuel Systems
    4. 4.4 Sources of Data for Biofuels Process Design
    5. 4.5 Methods for Predicting Data for Biofuels Process Design
    6. 4.6 Challenges for the Biofuels Process Design Methods
    7. 4.7 Influence of Uncertainties in Thermophysical Properties of Pure Compounds on the Phase Behavior of Biofuel Systems
    8. 4.8 Conclusions
    9. Acknowledgment
    10. Exercises
    11. References
  10. 5 Up‐grading of Waste Oil: A Key Step in the Future of Biofuel Production
    1. 5.1 Introduction
    2. 5.2 Physicochemical Pretreatments of Waste Oils: Removal of Contaminants
    3. 5.3 Direct Treatment and Conversion of FFAs into Methyl Esters
    4. 5.4 Future Trends of the Pretreatments of Waste Oils
    5. 5.5 Conclusions
    6. Acknowledgment
    7. Abbreviations
    8. References
  11. 6 Production of Biojet Fuel from Waste Raw Materials: A Review
    1. 6.1 Introduction
    2. 6.2 Waste Triglyceride Feedstock
    3. 6.3 Waste Lignocellulosic Feedstock
    4. 6.4 Waste Sugar and Starchy Feedstock
    5. 6.5 Main Challenges and Future Trends
    6. 6.6 Conclusions
    7. Acknowledgments
    8. References
  12. 7 Computer‐Aided Design for Genetic Modulation to Improve Biofuel Production
    1. 7.1 Introduction
    2. 7.2 Method
    3. 7.3 Computer‐Aided Strain Design Tool
    4. 7.4 Examples
    5. 7.5 Conclusions
    6. Appendix 7.A The SBP Program
    7. References
  13. 8 Implementation of Biodiesel Production Process Using Enzyme‐Catalyzed Routes
    1. 8.1 Introduction
    2. 8.2 Biodiesel Production Routes: Chemical versus Enzymatic Catalysts
    3. 8.3 Optimal Reaction Conditions and Kinetic Modeling
    4. 8.4 Process Simulation and Economic Evaluation
    5. 8.5 Reuse of Enzyme for the Transesterification Reaction
    6. 8.6 Environmental Impact and Final Remarks
    7. Acknowledgments
    8. Nomenclature
    9. References
  14. 9 Process Analysis of Biodiesel Production – Kinetic Modeling, Simulation, and Process Design
    1. 9.1 Introduction
    2. 9.2 Getting Started with Aspen Plus V10
    3. 9.3 Kinetic Study
    4. 9.4 Process Design
    5. 9.5 Energy and Economic Analysis
    6. 9.6 Concluding Remarks
    7. Acknowledgment
    8. Exercises
    9. References
  15. 10 Process Development, Design and Analysis of Microalgal Biodiesel Production Aided by Microwave and Ultrasonication
    1. 10.1 Introduction
    2. 10.2 Process Development and Modeling
    3. 10.3 Sizing and Cost Analysis
    4. 10.4 Comparison with the WCO‐Based Process of the Same Capacity
    5. 10.5 Comparison with the Microalgae‐Based Processes
    6. 10.6 Conclusions
    7. Acknowledgment
    8. Appendix 10.A
    9. Exercises
    10. References
  16. 11 Thermochemical Processes for the Transformation of Biomass into Biofuels
    1. 11.1 Introduction
    2. 11.2 Biomass and Biofuels
    3. 11.3 Combustion
    4. 11.4 Gasification
    5. 11.5 Liquefaction
    6. 11.6 Pyrolysis
    7. 11.7 Carbonization
    8. 11.8 Conclusions
    9. Acknowledgments
    10. References
  17. 12 Intensified Purification Alternative for Methyl Ethyl Ketone Production: Economic, Environmental, Safety and Control Issues
    1. 12.1 Introduction
    2. 12.2 Problem Statement and Case Study
    3. 12.3 Evaluation Indexes and Optimization Problem
    4. 12.4 Global Optimization Methodology
    5. 12.5 Results
    6. 12.6 Conclusions
    7. Acknowledgments
    8. References
  18. 13 Present and Future of Biofuels
    1. 13.1 Introduction
    2. 13.2 Some Representative Biofuels
    3. 13.3 Perspectives and Future of Biofuels
    4. References
  19. Index
  20. End User License Agreement
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