- Title Page
- Copyright Page
- Dedicated to
- Contents
- Preface
- About the Author
- Chapter 1. Mole Balances
- Chapter 2. Conversion and Reactor Sizing
- Chapter 2. Conversion and Reactor Sizing
- 2.3.1 CSTR (Also Known as a Backmix Reactor or a Vat)
- 2.3.2 Tubular Flow Reactor (PFR)
- 2.3.3 Packed-Bed Reactor (PBR)
- 2.5.1 CSTRs in Series
- 2.5.2 PFRs in Series
- 2.5.3 Combinations of CSTRs and PFRs in Series
- 2.5.4 Comparing the CSTR and PFR Reactor Volumes and Reactor Sequencing
- 2.6.1 Space Time
- 2.6.2 Space Velocity
- Chapter 3. Rate Laws
- Chapter 4. Stoichiometry
- Chapter 5. Isothermal Reactor Design: Conversion
- Chapter 6. Isothermal Reactor Design: Molar Flow Rates
- Chapter 7. Collection and Analysis of Rate Data
- Chapter 8. Multiple Reactions
- Chapter 8. Multiple Reactions
- 8.1.1 Types of Reactions
- 8.1.2 Selectivity
- 8.1.3 Yield
- 8.2.1 Modifications to the Chapter 6 CRE Algorithm for Multiple Reactions
- 8.3.1 Selectivity
- 8.3.2 Maximizing the Desired Product for One Reactant
- 8.3.3 Reactor Selection and Operating Conditions
- 8.5.1 Complex Reactions in a PBR
- 8.5.2 Multiple Reactions in a CSTR
- Chapter 9. Reaction Mechanisms, Pathways, Bioreactions, and Bioreactors
- Chapter 9. Reaction Mechanisms, Pathways, Bioreactions, and Bioreactors
- 9.1.1 Pseudo-Steady-State Hypothesis (PSSH)
- 9.1.2 Searching for a Mechanism
- 9.1.3 Chain Reactions
- 9.2.1 Enzyme–Substrate Complex
- 9.2.2 Mechanisms
- 9.2.3 Michaelis–Menten Equation
- 9.2.4 Batch Reactor Calculations for Enzyme Reactions
- 9.3.1 Competitive Inhibition
- 9.3.2 Uncompetitive Inhibition
- 9.3.3 Noncompetitive Inhibition (Mixed Inhibition)12
- 9.3.4 Substrate Inhibition
- Cell Growth and Division
- 9.4.1 Cell Growth
- 9.4.2 Rate Laws
- 9.4.3 Stoichiometry
- 9.4.4 Mass Balances
- 9.4.5 Chemostats
- 9.4.6 CSTR Bioreactor Operation
- 9.4.7 Wash-Out
- Chapter 10. Catalysis and Catalytic Reactors
- Chapter 10. Catalysis and Catalytic Reactors
- 10.1.1 Definitions
- 10.1.2 Catalyst Properties
- 10.1.3 Catalytic Gas-Solid Interactions
- 10.1.4 Classification of Catalysts
- Where Are We Heading?
- 10.2.1 Step 1 Overview: Diffusion from the Bulk to the External Surface of the Catalyst
- 10.2.2 Step 2 Overview: Internal Diffusion
- 10.2.3 Adsorption Isotherms
- 10.2.4 Surface Reaction
- 10.2.5 Desorption
- 10.2.6 The Rate-Limiting Step
- 10.3.1 Is the Adsorption of Cumene Rate-Limiting?
- 10.3.2 Is the Surface Reaction Rate-Limiting?
- 10.3.3 Is the Desorption of Benzene Rate-Limiting?
- 10.3.4 Summary of the Cumene Decomposition
- 10.3.5 Reforming Catalysts
- 10.3.6 Rate Laws Derived from the Pseudo-Steady-State Hypothesis (PSSH)
- 10.3.7 Temperature Dependence of the Rate Law
- 10.4.1 Deducing a Rate Law from the Experimental Data
- 10.4.2 Finding a Mechanism Consistent with Experimental Observations
- 10.4.3 Evaluation of the Rate Law Parameters
- 10.4.4 Reactor Design
- 10.5.1 Overview
- 10.5.2 Chemical Vapor Deposition
- Chapter 11. Nonisothermal Reactor Design–The Steady State Energy Balance and Adiabatic PFR Applications
- Chapter 11. Nonisothermal Reactor Design–The Steady State Energy Balance and Adiabatic PFR Applications
- 11.2.1 First Law of Thermodynamics
- 11.2.2 Evaluating the Work Term
- 11.2.3 Overview of Energy Balances
- 11.3.1 Dissecting the Steady-State Molar Flow Rates to Obtain the Heat of Reaction
- 11.3.2 Dissecting the Enthalpies
- 11.3.3 Relating ΔHRx(T), , and ΔCP
- 11.4.1 Adiabatic Energy Balance
- 11.4.2 Adiabatic Tubular Reactor
- 11.5.1 Equilibrium Conversion
- 11.5.2 Reactor Staging
- Chapter 12. Steady-State Nonisothermal Reactor Design—Flow Reactors with Heat Exchange
- Chapter 12. Steady-State Nonisothermal Reactor Design—Flow Reactors with Heat Exchange
- 12.1.1 Deriving the Energy Balance for a PFR
- 12.2.1 Co-Current Flow
- 12.2.2 Counter Current Flow
- 12.3.1 Applying the Algorithm to an Exothermic Reaction
- 12.3.2 Applying the Algorithm to an Endothermic Reaction
- 12.4.1 Heat Added to the Reactor,
- 12.5.1 Heat-Removed Term, R(T)
- 12.5.2 Heat-Generated Term, G(T)
- 12.5.3 Ignition-Extinction Curve
- 12.6.1 Energy Balance for Multiple Reactions in Plug-Flow Reactors
- 12.6.2 Parallel Reactions in a PFR
- 12.6.3 Energy Balance for Multiple Reactions in a CSTR
- 12.6.4 Series Reactions in a CSTR
- 12.6.5 Complex Reactions in a PFR
- Chapter 13. Unsteady-State Nonisothermal Reactor Design
- Appendices
- Appendix A. Numerical Techniques
- Appendix B. Ideal Gas Constant and Conversion Factors
- Appendix C. Thermodynamic Relationships Involving the Equilibrium Constant
- Appendix D. Nomenclature
- Appendix E. Software Packages
- Appendix F. Rate Law Data
- Appendix G. Open-Ended Problems
- Appendix H. How to Use the DVD-ROM
- Index
- About the DVD-ROM
- Footnotes
Essentials of Chemical Reaction Engineering
H. Scott Fogler
Ame and Catherine Vennema Professor of Chemical Engineering
and the Arthur F. Thurnau Professor
The University of Michigan, Ann Arbor
Upper Saddle River, NJ • Boston • Indianapolis • San Francisco
New York • Toronto • Montreal • London • Munich • Paris • Madrid
Capetown • Sydney • Tokyo • Singapore • Mexico City
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