Contents
Chapter 1 Scope and Language of Thermodynamics
1.1 Molecular Basis of Thermodynamics
1.2 Statistical versus Classical Thermodynamics
Chapter 2 Phase Diagrams of Pure Fluids
2.1 The PVT Behavior of Pure Fluid
2.3 Compressibility Factor and the ZP Graph
2.7 PVT Behavior of Cubic Equations of State
2.8 Working with Cubic Equations
2.10 Thermal Expansion and Isothermal Compression
2.11 Empirical Equations for Density
Chapter 3 Energy and the First Law
3.1 Energy and Mechanical Work
3.4 First Law for a Closed System
3.6 Sensible Heat—Heat Capacities
3.9 Energy Balances and Irreversible Processes
Chapter 4 Entropy and the Second Law
4.1 The Second Law in a Closed System
4.3 Energy Balances Using Entropy
4.6 Alternative Statements of the Second Law
4.8 Ambient Surroundings as a Default Bath—Exergy
4.10 Molecular View of Entropy
Chapter 5 Calculation of Properties
5.1 Calculus of Thermodynamics
5.2 Integration of Differentials
5.4 Equations for Enthalpy and Entropy
5.8 Pressure-Explicit Relations
5.9 Application to Cubic Equations
Chapter 6 Balances in Open Systems
6.3 Energy Balance in Open System
6.6 Thermodynamics of Steady-State Processes
7.5 Saturation Pressure from Equations of State
7.6 Phase Diagrams from Equations of State
Chapter 8 Phase Behavior of Mixtures
8.5 VLE at Elevated Pressures and Temperatures
8.6 Partially Miscible Liquids
Chapter 9 Properties of Mixtures
9.2 Mathematical Treatment of Mixtures
9.5 Mixtures in the Ideal-Gas State
9.6 Equations of State for Mixtures
9.7 Mixture Properties from Equations of State
Chapter 10 Theory of Vapor-Liquid Equilibrium
10.1 Gibbs Free Energy of Mixture
10.4 Fugacity from Equations of State
10.5 VLE of Mixture Using Equations of State
11.2 Fugacity in Ideal Solution
11.3 VLE in Ideal Solution–Raoult’s Law
12.4 Activity Coefficient and Phase Equilibrium
12.5 Data Reduction: Fitting Experimental Activity Coefficients
12.6 Models for the Activity Coefficient
Chapter 13 Miscibility, Solubility, and Other Phase Equilibria
13.1 Equilibrium between Partially Miscible Liquids
13.2 Gibbs Free Energy and Phase Splitting
13.3 Liquid Miscibility and Temperature
13.4 Completely Immiscible Liquids
13.5 Solubility of Gases in Liquids
13.6 Solubility of Solids in Liquids
14.2 Standard Enthalpy of Reaction
14.3 Energy Balances in Reacting Systems
14.6 Composition at Equilibrium
14.7 Reaction and Phase Equilibrium
14.8 Reaction Equilibrium Involving Solids
Appendix A Critical Properties of Selected Compounds
Appendix B Ideal-Gas Heat Capacities
Appendix C Standard Enthalpy and Gibbs Free Energy of Reaction