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by Raj Rajagopalan, Paul C. Hiemenz
Principles of Colloid and Surface Chemistry, Revised and Expanded, 3rd Edition
Cover
Half Title
Title Page
Copyright Page
Table of Contents
Preface to the Third Edition
Acknowledgments
Preface to the Second Edition
Preface to the First Edition
1. Colloid and Surface Chemistry: Scope and Variables
1.1 Introduction
1.2 The Importance of the Surface for Small Particles
1.3 Classification of Colloids Based on Affinity to Carrier Fluid
1.4 Concept of Stability of Colloidal Systems
1.5 Some Physical Characteristics of Colloids
1.6 Some Classical and Emerging Experimental Tools
1.7 An Overview of the Book
Review Questions
References
Problems
2. Sedimentation and Diffusion and Their Equilibrium
2.1 Introduction
2.2 Sedimentation: Some Basic Considerations
2.3 Gravitational Sedimentation
2.4 Centrifugal Sedimentation
2.5 Diffusion
2.6 Brownian Motion and Diffusion
2.7 The Random Coil and Random Walk Statistics
2.8 Equilibrium Between Sedimentation and Diffusion
Review Questions
References
Problems
3. Solution Thermodynamics: Osmotic and Donnan Equilibria
3.1 Introduction
3.2 Osmotic Pressure: Thermodynamic Foundations
3.3 Osmometry: Some Applications
3.4 Statistical Foundations of Solution Thermodynamics
3.5 Osmotic Equilibrium in Charged Systems
3.6 Some Applications of Osmotic Phenomena
Review Questions
References
Problems
4. The Rheology of Dispersions
4.1 Introduction
4.2 Newton’s Law of Viscosity
4.3 Concentric-Cylinder and Cone-and-Plate Viscometers
4.4 The Poiseuille Equation and Capillary Viscometers
4.5 The Equation of Motion: The Navier-Stokes Equation
4.6 Einstein’s Theory of Viscosity of Dispersions
4.7 Deviations from the Einstein Model
4.8 Non-Newtonian Behavior
4.9 Viscosity of Polymer Solutions
Review Questions
References
Problems
5. Static and Dynamic Light Scattering and Other Radiation Scattering
5.1 Introduction
5.2 Interaction of Radiation with Matter
5.3 Scattering by Small Particles: Theory of Rayleigh Scattering
5.4 Experimental Aspects of Light Scattering
5.5 Extension to Larger Particles and to Intraparticle Interference Effects
5.6 Interference Effects and Structure of Particles
5.7 Scattering by Large, Absorbing Particles
5.8 Dynamic Light Scattering
Review Questions
References
Problems
6. Surface Tension and Contact Angle: Application to Pure Substances
6.1 Introduction
6.2 Surface Tension and Contact Angle: A First Look
6.3 Thermodynamics of Surfaces: Surface Tension as Surface Free Energy
6.4 Surface Tension: Implications for Curved Interfaces and Capillarity
6.5 Effects of Curved Interfaces on Phase Equilibria and Nucleation: The Kelvin Equation
6.6 Surface Tension and Contact Angle: Their Relation to Wetting and Spreading Phenomena
6.7 Contact Angles: Some Complications
6.8 Measuring Surface Tension and Contact Angle: Round Two
6.9 Contact of Liquids with Porous Solids and Powders
6.10 Molecular Interpretation of Surface Tension
Review Questions
References
Problems
7. Adsorption from Solution and Monolayer Formation
7.1 Introduction
7.2 Insoluble Monolayers: Spreading of Surfactants on Aqueous Surfaces
7.3 Experimental Measurement of Film Pressure
7.4 Results of Film Balance Studies
7.5 Viscous Behavior of Two-Dimensional Phases
7.6 Applications of Monolayers and Monolayer Concepts
7.7 Adsorption from Solution: Thermodynamics
7.8 The Gibbs Equation: Experimental Results
7.9 Adsorption on Solid Surfaces
7.10 Applications of Adsorption from Solution
7.11 Adsorption in the Presence of an Applied Potential
Review Questions
References
Problems
8. Colloidal Structures in Surfactant Solutions: Association Colloids
8.1 Introduction
8.2 Surfactants in Solution: Experimental Observations and Models
8.3 Structure of Micelles
8.4 Molecular Architecture of Surfactants, Packing Considerations, and Shapes of Micelles
8.5 Critical Micelle Concentration and the Thermodynamics of Micellization
8.6 Solubilization
8.7 Catalysis by Micelles
8.8 Reverse Micelles
8.9 Emulsions and Microemulsions
8.10 Some Applications of Microemulsions
8.11 Biological Membranes
Review Questions
References
Problems
9. Adsorption at Gas–Solid Interfaces
9.1 Introduction
9.2 Experimental and Theoretical Treatments of Adsorption: An Overview
9.3 Thermodynamics of Adsorption: Phenomenological Perspective
9.4 Thermodynamics of Adsorption: A Statistical Perspective
9.5 Multilayer Adsorption: The Brunauer-Emmett-Teller Equation
9.6 Energetics of Adsorption
9.7 Adsorption in Porous Solids
9.8 Adsorption on Crystal Surfaces
9.9 Metal Surfaces and Heterogeneous Catalysis
Review Questions
References
Problems
10. van der Waals Forces
10.1 Introduction
10.2 van der Waals Forces and Their Importance in Colloid and Surface Chemistry
10.3 Molecular Interactions and Power Laws
10.4 Molecular Origins and the Macroscopic Implications of van der Waals Forces
10.5 van der Waals Forces Between Large Particles and Over Large Distances
10.6 Calculating van der Waals Forces Between Macroscopic Bodies
10.7 Theories of van der Waals Forces Based on Bulk Properties
10.8 Effect of the Medium on the van der Waals Attraction
Review Questions
References
Problems
11. The Electrical Double Layer and Double-Layer Interactions
11.1 Introduction
11.2 Surface Charges and Electrical Double Layer: Background
11.3 The Capacitor Model of the Double Layer
11.4 The Diffuse Double Layer: The Debye-Huckel Approximation
11.5 The Debye-Hückel Approximation: Results
11.6 The Electrical Double Layer: Gouy-Chapman Theory
11.7 Overlapping Double Layers and Interparticle Repulsion
11.8 “Not-Quite-Indifferent” Electrolytes: Stern Adsorption
Review Questions
References
Problems
12. Electrophoresis and Other Electrokinetic Phenomena
12.1 Introduction
12.2 Mobilities of Small Ions and Macroions in Electric Fields: A Comparison
12.3 Zeta Potential: Thick Electrical Double Layers
12.4 Zeta Potential: Thin Electrical Double Layers
12.5 Zeta Potential: General Theory for Spherical Particles
12.6 Electroosmosis
12.7 Streaming Potential
12.8 The Surface of Shear and Viscoelectric Effect
12.9 Experimental Aspects of Electrophoresis
12.10 Determining the Surface Charge from Electrokinetic Measurements
12.11 Applications of Electrokinetic Phenomena
Review Questions
References
Problems
13. Electrostatic and Polymer-Induced Colloid Stability
13.1 Introduction
13.2 Interparticle Forces and the Structure and Stability of Dispersions
13.3 The Derjaguin-Landau-Verwey-Overbeek Theory of Colloid Stability
13.4 Theory of Coagulation in Dilute Dispersions
13.5 Polymer-Colloid Mixtures: A Phenomenological Perspective
13.6 Polymer-Induced Forces
13.7 Steric Stabilization: A Model for the Initial Encounter
Review Questions
References
Problems
Appendix A: Examples of Expansions Encountered in This Book
Reference
Appendix B: Units: CGS-SI Interconversions
References
Appendix C: Statistics of Discrete and Continuous Distributions of Data
C.1 Introduction
C.2 Discrete Distributions
C.3 Theoretical Distribution Functions
References
Appendix D: List of Worked-Out Examples
Index
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