- Cover
- Title Page
- Copyright
- Preface
- List of Symbols
- About the Companion Website
- Chapter 1: Introduction and Basic Principles
- 1.1 Electrochemical Cells
- 1.2 Characteristics of Electrochemical Reactions
- 1.3 Importance of Electrochemical Systems
- 1.4 Scientific Units, Constants, Conventions
- 1.5 Faraday's Law
- 1.6 Faradaic Efficiency
- 1.7 Current Density
- 1.8 Potential and OHM'S Law
- 1.9 Electrochemical Systems: Example
- Closure
- Further Reading
- Problems
- Chapter 2: Cell Potential and Thermodynamics
- 2.1 Electrochemical Reactions
- 2.2 Cell Potential
- 2.3 Expression for Cell Potential
- 2.4 Standard Potentials
- 2.5 Effect of Temperature on Standard Potential
- 2.6 Simplified Activity Correction
- 2.7 Use of the Cell Potential
- 2.8 Equilibrium Constants
- 2.9 Pourbaix Diagrams
- 2.10 Cells with a Liquid Junction
- 2.11 Reference Electrodes
- 2.12 Equilibrium at Electrode Interface
- 2.13 Potential in Solution Due to Charge: Debye–Hückel Theory
- 2.14 Activities and Activity Coefficients
- 2.15 Estimation of Activity Coefficients
- Closure
- Further Reading
- Problems
- Chapter 3: Electrochemical Kinetics
- 3.1 Double Layer
- 3.2 Impact of Potential on Reaction Rate
- 3.3 Use of the Butler–Volmer Kinetic Expression
- 3.4 Reaction Fundamentals
- 3.5 Simplified forms of the Butler–Volmer Equation
- 3.6 Direct Fitting of the Butler–Volmer Equation
- 3.7 The Influence of Mass Transfer on the Reaction Rate
- 3.8 Use of Kinetic Expressions in Full Cells
- 3.9 Current Efficiency
- Closure
- Further Reading
- Problems
- Chapter 4: Transport
- Chapter 5: Electrode Structures and Configurations
- 5.1 Mathematical Description of Porous Electrodes
- 5.2 Characterization of Porous Electrodes
- 5.3 Impact of Porous Electrode on Transport
- 5.4 Current Distributions in Porous Electrodes
- 5.5 The Gas–Liquid Interface in Porous Electrodes
- 5.6 Three-Phase Electrodes
- 5.7 Electrodes with Flow
- Closure
- Further Reading
- Problems
- Chapter 6: Electroanalytical Techniques and Analysis of Electrochemical Systems
- 6.1 Electrochemical Cells, Instrumentation, and Some Practical Issues
- 6.2 Overview
- 6.3 Step Change in Potential or Current for a Semi-Infinite Planar Electrode in a Stagnant Electrolyte
- 6.4 Electrode Kinetics and Double-Layer Charging
- 6.5 Cyclic Voltammetry
- 6.6 Stripping Analyses
- 6.7 Electrochemical Impedance
- 6.8 Rotating Disk Electrodes
- 6.9 iR Compensation
- 6.10 Microelectrodes
- Closure
- Further Reading
- Problems
- Chapter 7: Battery Fundamentals
- 7.1 Components of a Cell
- 7.2 Classification of Batteries and Cell Chemistries
- 7.3 Theoretical Capacity and State of Charge
- 7.4 Cell Characteristics and Electrochemical Performance
- 7.5 Ragone Plots
- 7.6 Heat Generation
- 7.7 Efficiency of Secondary Cells
- 7.8 Charge Retention and Self-Discharge
- 7.9 Capacity Fade in Secondary Cells
- Closure
- Further Reading
- Problems
- Chapter 8: Battery Applications: Cell and Battery Pack Design
- 8.1 Introduction to Battery Design
- 8.2 Battery Layout Using a Specific Cell Design
- 8.3 Scaling of Cells to Adjust Capacity
- 8.4 Electrode and Cell Design to Achieve Rate Capability
- 8.5 Cell Construction
- 8.6 Charging of Batteries
- 8.7 Use of Resistance to Characterize Battery Peformance
- 8.8 Battery Management
- 8.9 Thermal Management Systems
- 8.10 Mechanical Considerations
- Closure
- Further Reading
- Problems
- Chapter 9: Fuel-Cell Fundamentals
- Chapter 10: Fuel-Cell Stack and System Design
- 10.1 Introduction and Overview of Systems Analysis
- 10.2 Basic Stack Design Concepts
- 10.3 Cell Stack Configurations
- 10.4 Basic Construction and Components
- 10.5 Utilization of Oxidant and Fuel
- 10.6 Flow-Field Design
- 10.7 Water and Thermal Management
- 10.8 Structural–Mechanical Considerations
- 10.9 Case Study
- Closure
- Further Reading
- Problems
- Chapter 11: Electrochemical Double-Layer Capacitors
- 11.1 Capacitor Introduction
- 11.2 Electrical Double-Layer Capacitance
- 11.3 Current–Voltage Relationship for Capacitors
- 11.4 Porous Edlc Electrodes
- 11.5 Impedance Analysis of EDLCs
- 11.6 Full Cell Edlc Analysis
- 11.7 Power and Energy Capabilities
- 11.8 Cell Design, Practical Operation, and Electrochemical Capacitor Performance
- 11.9 Pseudo-Capacitance
- Closure
- Further Reading
- Problems
- Chapter 12: Energy Storage and Conversion for Hybrid and Electrical Vehicles
- 12.1 Why Electric and Hybrid-Electric Systems?
- 12.2 Driving Schedules and Power Demand in Vehicles
- 12.3 Regenerative Braking
- 12.4 Battery Electrical Vehicle
- 12.5 Hybrid Vehicle Architectures
- 12.6 Start–Stop Hybrid
- 12.7 Batteries for Full-Hybrid Electric Vehicles
- 12.8 Fuel-Cell Hybrid Systems for Vehicles
- Closure
- Note
- Further Reading
- Problems
- Chapter 13: Electrodeposition
- 13.1 Overview
- 13.2 Faraday's Law and Deposit Thickness
- 13.3 Electrodeposition Fundamentals
- 13.4 Formation of Stable Nuclei
- 13.5 Nucleation Rates
- 13.6 Growth of Nuclei
- 13.7 Deposit Morphology
- 13.8 Additives
- 13.9 Impact of Current Distribution
- 13.10 Impact of Side Reactions
- 13.11 Resistive Substrates
- Closure
- Further Reading
- Problems
- Chapter 14: Industrial Electrolysis, Electrochemical Reactors, and Redox-Flow Batteries
- 14.1 Overview of Industrial Electrolysis
- 14.2 Performance Measures
- 14.3 Voltage Losses and the Polarization Curve
- 14.4 Design of Electrochemical Reactors for Industrial Applications
- 14.5 Examples of Industrial Electrolytic Processes
- 14.6 Thermal Management and Cell Operation
- 14.7 Electrolytic Processes for a Sustainable Future
- 14.8 Redox-Flow Batteries
- Closure
- Further Reading
- Problems
- Chapter 15: Semiconductor Electrodes and Photoelectrochemical Cells
- Chapter 16: Corrosion
- Appendix A: Electrochemical Reactions and Standard Potentials
- Appendix B: Fundamental Constants
- Appendix C: Thermodynamic Data
- Appendix D: Mechanics of Materials
- Index
- End User License Agreement
About the Companion Website
This book is accompanied by a companion website:
The website features:
- Powerpoint slides for figures from the text
- Complete solution manual to end of chapter problems
- Excel files for data sets used in student problems and chapter illustrations
-
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