Contents

Foreword

Preface

Acknowledgments

About the Author

Chapter 1 Introduction to Energy Systems

1.1 Energy and Society

1.2 Energy System Architecture

1.3 Evolution of Energy Systems

1.3.1 Fossil Sources: Resource Limitations and Climate Change

1.3.2 Nuclear Energy: Economics, Safety, and Waste Management

1.4 Future Energy Systems: Growth of Renewables

1.5 Summary

Chapter 2 Renewable Energy Sources

2.1 Primary Renewable Energy Sources

2.1.1 Solar Energy

2.1.2 Geothermal Energy

2.1.3 Biomass Energy

2.1.4 Hydropower Energy

2.1.5 Wind Energy

2.2 Transformations of Primary Renewable Energy Sources

2.2.1 Transformations of Mechanical Energy Sources

2.2.2 Transformations of Geothermal Energy

2.2.3 Transformations of Solar Energy

2.2.4 Transformations of Biomass Energy

2.3 Summary

Chapter 3 Transformations and Chemical Processes in Solar Energy Systems

3.1 Solar Thermal (CSP) Systems

3.1.1 CSP Configurations

3.1.2 Chemistry and Processing of Solar Heat Exchange Media

3.1.2.1 Thermal Oils

3.1.2.2 Molten Salts

3.1.2.3 Liquid Metals

3.2 Solar PV Systems

3.2.1 PV Effect and Fundamental Structure of a PV Cell

3.2.2 PV Cell Technology

3.2.2.1 Efficiency of PV Cells

3.2.2.2 Materials for PV Cells

3.2.3 Chemistry and Processing of PV Cell Materials

3.2.3.1 PV-Grade Silicon

3.2.3.2 Amorphous Silicon and Gen 2 Thin Films

3.2.3.3 Perovskites

3.3 Summary

Chapter 4 Transformations and Chemical Processes in Biomass Energy Systems

4.1 Biomass Characteristics

4.1.1 Chemical Structure of Biomass

4.1.1.1 Carbohydrates

4.1.1.2 Lignin

4.1.1.3 Protein

4.1.1.4 Lipids

4.1.1.5 Ash

4.1.1.6 Extractives

4.1.2 Physical Structure of Biomass

4.1.3 Implications of Biomass Composition and Structure on Processing for Bioenergy Applications

4.2 Biomass Pretreatment

4.2.1 Physical Pretreatment

4.2.2 Chemical Pretreatment

4.2.3 Physicochemical Pretreatment

4.2.4 Biological Pretreatment

4.2.5 Pretreatment of Algal Biomass

4.3 Biomass Transformations

4.3.1 Thermochemical Processing of Biomass

4.3.1.1 Combustion

4.3.1.2 Gasification

4.3.1.3 Pyrolysis

4.3.1.4 Hydrotreating

4.3.2 Biochemical Processing of Biomass

4.3.2.1 Enzymatic Hydrolysis of Biomass

4.3.2.2 Fermentation of Sugars

4.3.2.3 Anaerobic Digestion

4.3.3 Biomass Lipid Extraction and Conversion to Biodiesel

4.3.4 Generation 4 of Biomass Energy Systems—Emerging Technologies

4.4 Summary

Chapter 5 Transformations and Chemical Processes in Mechanical, Geothermal, and Ocean Energy Systems

5.1 Transformations of Mechanical Energy

5.1.1 Hydropower—Transformation of Potential Energy

5.1.2 Wind Power—Transformation of Kinetic Energy

5.2 Transformations of Geothermal Energy

5.2.1 Classification and Characteristics of Geothermal Resources

5.2.2 Energy Conversion Technologies

5.2.2.1 Steam-Driven Plants

5.2.2.2 Binary Cycle Plants

5.3 Transformations of Ocean Energy

5.3.1 Potential Energy Transformations

5.3.2 Kinetic Energy Transformations

5.3.2.1 Tidal Current Energy

5.3.2.2 Wave Energy

5.3.3 Thermal Energy Transformations

5.3.4 Chemical Energy Transformations

5.3.4.1 Pressure-Retarded Osmosis

5.3.4.2 Reverse Electrodialysis

5.3.4.3 Capacitive Mixing

5.3.4.4 Capacitive Reverse Electrodialysis

5.4 Summary

Chapter 6 Hybrid Energy Systems

6.1 Intermittency in Renewable Energy Systems: Causes and Impacts

6.2 HES: Definition and Architecture

6.3 Energy Storage: Fundamentals and Alternatives

6.3.1 Direct Energy Storage

6.3.2 Indirect Energy Storage

6.3.2.1 Storage by Conversion into Mechanical Energy

6.3.2.2 Storage by Conversion into Chemical Energy

6.3.2.3 Storage by Conversion into Thermal Energy

6.3.3 Characteristics and Applications of Energy Storage Systems

6.4 Separations and Processes in Chemical Energy Storage

6.4.1 Electrochemical Energy Storage

6.4.1.1 Lead–Acid Battery

6.4.1.2 Ni–Cd Battery

6.4.1.3 Li-Ion Battery

6.4.1.4 Sodium–Sulfur (Na–S) Battery

6.4.1.5 Vanadium Redox Battery

6.4.1.6 Comparison of Electrochemical Storage Alternatives

6.4.2 Chemical Energy Storage

6.4.2.1 Hydrogen

6.4.2.2 Methanol

6.4.2.3 Methane

6.4.2.4 Ethanol

6.4.2.5 Merits and Demerits of Chemical Energy Storage Alternatives

6.4.2.6 Fuel Cells: Conversion of Chemical Energy to Electrical Energy

6.5 Separations and Processes in TES

6.5.1 Sensible Heat Storage Systems

6.5.2 Latent Heat Storage Systems

6.5.3 TCS Systems

6.5.4 Comparison of TES Systems and Applications in RESs

6.6 Summary

Chapter 7 Techno-Economic Analysis of Renewable Energy Systems

7.1 Current Status of Renewable Energy Systems

7.2 Economics and Energy Balance of Energy Systems

7.2.1 Levelized Cost of Electricity

7.2.2 Overnight Cost of Power Plant

7.2.3 Energy Return on Energy Investment

7.3 Environmental Impacts of Renewable Energy Systems

7.4 Role of Public Policy in Energy Transitions

7.4.1 The United States

7.4.2 The European Union

7.4.2.1 Germany

7.4.2.2 France

7.4.3 China

7.4.4 India

7.4.5 Brazil

7.4.6 Strategies for Expansion of Renewable Energy

7.4.6.1 Feed-in Tariffs

7.4.6.2 Renewable Portfolio Standards

7.4.6.3 Financial Incentives

7.4.6.4 Carbon Pricing

7.5 Summary

Epilogue The Path Forward

Appendix A Conversion Factors and Constants

Appendix B Thermodynamic Power Cycles: A Primer

Index

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