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by Takashi Kato, Hisashi Yamamoto
Molecular Technology, Volume 1
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Foreword by Dr Hamaguchi
Foreword by Dr Noyori
Preface
Chapter 1: Charge Transport Simulations for Organic Semiconductors
1.1 Introduction
1.2 Theoretical Description of Charge Transport in Organic Semiconductors
1.3 Charge Transport Properties of Organic Semiconductors
1.4 Summary
Acknowledgments
References
Chapter 2: Liquid‐Phase Interfacial Synthesis of Highly Oriented Crystalline Molecular Nanosheets
2.1 Introduction
2.2 Molecular Nanosheet Formation with Traditional Surfactants at Air/Liquid Interfaces
2.3 Application of Functional Organic Molecules for Nanosheet Formation at Air/Liquid Interfaces
2.4 Porphyrin‐Based Metal–Organic Framework (MOF) Nanosheet Crystals Assembled at Air/Liquid Interfaces
References
Chapter 3: Molecular Technology for Organic Semiconductors Toward Printed and Flexible Electronics
3.1 Introduction
3.2 Molecular Design and Favorable Aggregated Structure for Effective Charge Transport of Organic Semiconductors
3.3 Molecular Design of Linearly Fused Acene‐Type Molecules
3.4 Molecular Technology of π‐Conjugated Cores for p-Type Organic Semiconductors
3.5 Molecular Technology of Substituents for Organic Semiconductors
3.6 Molecular Technology of Conceptually‐new Bent‐shaped π‐Conjugated Cores for p‐Type Organic Semiconductors
3.7 Molecular Technology for n‐Type Organic Semiconductors
References
Chapter 4: Design of Multiproton‐Responsive Metal Complexes as Molecular Technology for Transformation of Small Molecules
4.1 Introduction
4.2 Cooperation of Metal and Functional Groups in Metalloenzymes
4.3 Proton‐Responsive Metal Complexes with Two Appended Protic Groups
4.4 Proton‐Responsive Metal Complexes with Three Appended Protic Groups on Tripodal Scaffolds
4.5 Summary and Outlook
Acknowledgments
References
Chapter 5: Photo‐Control of Molecular Alignment for Photonic and Mechanical Applications
5.1 Introduction
5.2 Photo‐Chemical Alignment
5.3 Photo‐Physical Alignment
5.4 Photo‐Physico‐Chemical Alignment
5.5 Application as Photo‐Actuators
5.6 Conclusions and Perspectives
References
Chapter 6: Molecular Technology for Chirality Control: From Structure to Circular Polarization
6.1 Chiral Lanthanide(III) Complexes as Circularly Polarized Luminescence Materials
6.2 Magnetic Circular Dichroism and Magnetic Circularly Polarized Luminescence
6.3 Molecular Self‐assembled Helical Structures as Source of Circularly Polarized Light
6.4 Optical Activity Caused by Mesoscopic Chiral Structures and Microscopic Analysis of the Chiroptical Properties
6.5 Conclusions
References
Chapter 7: Molecular Technology of Excited Triplet State
7.1 Properties of the Triplet Exciton and Associated Phenomena for Molecular Technology
7.2 Near‐infrared‐to‐visible Photon Upconversion: Chromophore Development and Triplet Energy Migration
7.3 Singlet Exciton Fission Molecules and Their Application to Organic Photovoltaics
References
Chapter 8: Material Transfer and Spontaneous Motion in Mesoscopic Scale with Molecular Technology
8.1 Introduction
8.2 Mechanism to Originate Mesoscale Motion
8.3 Generation of “Molecular Power” by a Stimuli‐Responsive Molecule
8.4 Mesoscale Motion Generated by Cooperation of “Molecular Power”
8.5 Summary and Outlook
References
Chapter 9: Molecular Technologies for Photocatalytic CO2 Reduction
9.1 Introduction
9.2 Photocatalytic Systems Consisting of Mononuclear Metal Complexes
9.3 Supramolecular Photocatalysts: Multinuclear Complexes
9.4 Photocatalytic Reduction of Low Concentration of CO2
9.5 Hybrid Systems Consisting of the Supramolecular Photocatalyst and Semiconductor Photocatalysts
9.6 Conclusion
Acknowledgements
References
Chapter 10: Molecular Design of Photocathode Materials for Hydrogen Evolution and Carbon Dioxide Reduction
10.1 Introduction
10.2 Photocathode Materials for H2 Evolution
10.3 Photocathodes for CO2 Reduction Based on Molecular Catalysts
Acknowledgements
References
Chapter 11: Molecular Design of Glucose Biofuel Cell Electrodes
11.1 Introduction
11.2 Molecular Approaches for Enzymatic Electrocatalytic Oxidation of Glucose
11.3 Molecular Designs for Enhanced Electron Transfers with Oxygen‐Reducing Enzymes
11.4 Conclusion and Future Perspectives
References
Index
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