Table of Contents

Cover image

Title page

Copyright

Introduction

1. Interactions of ion beams with polymers: the physical picture

References

2. Ion implanters

Development of ion implanters

Sheath dynamics in plasma immersion ion implantation

Plasma immersion ion implantation of insulators

Estimating fluence and practical process considerations

References

3. Interactions of energetic ions with polymers: chemical picture

References

4. Structure of polymers after ion beam treatment

Color changes

Darkening as a measure of fluence

Carbonization of the surface layer

Raman spectroscopy analysis of the modified layer

Electron spin resonance spectroscopy analysis of structural changes

Fourier-transform infrared spectroscopy analysis of structural changes

Changes in surface energy

X-ray photoemission spectroscopy analysis of structural changes

X-ray diffraction for crystalline fractions

Analysis of cross-linking by gel-fraction measurements

Effects of structural changes on mechanical properties

Summary

References

5. Wetting

Wettability and surface energy: theory and measurement

Modification of wettability of polymers using ion implantation

Applications and relevant theoretical aspects of surface wetting

References

6. Adhesion

References

7. Hardness

Applications of polymers benefit from improved surface hardness

Mechanisms for hardness improvement by ion implantation

References

8. Ion beam synthesis

References

9. Biological and medical applications

References

10. Protection in an aggressive environment

References

11. Polymerization of liquid polymer matrix in free-space environment

Vacuum

Space plasma

Temperature variations

Microgravity

Meteorite fluency

References

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