Appendix D. Data Locations

This appendix gives the location of the large amount of data scattered throughout the textbook.

abietic acid-heptane-methylcellosolve + 10.0% water: Distribution coefficient, Table 13-3

acetic acid: Adsorption isotherm on activated carbon, Table 19-2 and Problem 19.D7

acetic acid-benzene-water: Distribution coefficients, Table 13-3

acetic acid-1-butanol-water: Distribution coefficient, Table 13-3

acetic acid-3-heptanol-water: Distribution coefficient, Problems 13.D5 and 13.D6

acetic acid-isopropyl ether-water: Equilibrium data, Table 13-5

acetic acid-water: Liquid-solid equilibrium, Figure 17-6

acetonaphthalene: Adsorption isotherm on silica gel, Table 19-2

acetone: Henry’s law constant in water, Problem 12.D1; adsorption isotherm on activated carbon, Problem 18.D12

acetone-benzene-chloroform: Distillation curves, Figure 8-8

acetone-chloroform-water: LLE, Table 13-4 and Figure 13-12

acetone-ethanol: VLE, Problem 4.D7

acetone-water: Solubility of proteins in, immediately after Eq. (17-49)

activated alumina: Properties as adsorbent, Table 19-1 and Examples 19-2, 19-6, and 19-7

activated carbon: Properties as adsorbent, Table 19-1, Example 19-4, and Problem 19.D7; isotherms for adsorption of hydrogen, methane, ethane, ethylene, and propane, Figure 19-2; hydrogen and methane adsorption isotherms, Example 19-4

adipic acid: Solubility in water, Problem 17.D2

air: Diffusivity in gases: ammonia, benzene, 2-butanol, n-butanol, carbon dioxide, chlorine, ethanol, n-hexane, hydrogen, naphthalene, n-octane, n-pentane, 2-pentanol, water, Table 15-1; diffusivity water in air, Problem 15.D6; diffusivity in liquid water, Table 15-3, MW = 28.9

alcohol dehydrogenase-aqueous 5.0% PEG-aqueous 10.0% dextran: Distribution -coefficient, Example 13-2

aluminium hydroxide, Al(OH)₃: Solubility product, Problem 17.D18

ammonia: Diffusivity in air, Table 15-1 and Problem 15.D10; diffusivity in hydrogen, Table 15-1; diffusivity in liquid water, Table 15-3; solubility in water, Table 12-3, Problem 12.D10, Example 15-10, and Problem 16.D12; density of liquid, Problem 10.D20

ammonium bromide: Solubility in water, Table 17-1

ammonium chloride: Solubility in water, Table 17-1

ammonium iodide: Solubility in water, Table 17-1

ammonium nitrate: Solubility in water, Table 17-1

ammonium sulfate: Solubility in water, Table 17-1

anions: Approximate equilibrium constants, Table 19-5

anthracene: MW = 178.22; adsorption isotherm on activated alumina, Table 19-2 and Examples 19-2, 19-6, and 19-7

argon: Solubility in liquid ammonia, Problem 12.D14

barium acetate: Solubility in water, Figure 17-3A

barium chloride: Solubility in water, Table 17-1, MW anhydrous = 208.23, MW hydrate = 244.25

benzene: VP and water solubility, Example 8-1; solubility parameter, paragraph following Eq. (13-1); diffusivity in air, Table 15-1; diffusivity in liquid ethanol, Table 15-3

benzene-acetone-chloroform: Distillation curves, Figure 8-8

benzene-ethanol-water: Residue curves, Figure 8-12

benzene-ethylene dichloride relative volatility: α_B–ED = 1.11

benzene-toluene relative volatility: Problem 4.G2

benzoic acid: Solubility in water, Table 17-1

benzoic acid-toluene-water: Diffusivity benzoic acid in water and in toluene and distribution coefficient between water and toluene, Examples 13-5 and 16-5 and Problem 15.D3; K_LD and K_O–ED, Example 16-5

bovine serum albumin: Adsorption isotherm on DEAE Sephadex A-50, Table 19-2

butane, iso-: K values, Figures 2-11 and 2-12, Table 2-3

butane, n-: K values, Figures 2-11 and 2-12, Table 2-3; vapor pressure, Problems 2.D14 and 5.D2; MW = 74.12; diffusivity in air, Table 15-1; λ, C_P,L, Problem 18.D14

butanol, 2-: Diffusivity in air, Table 15-1; diffusivity in liquid water, Table 15-3

butanol, n- n-propanol relative volatility: α_nB–nP = 0.412

butanol, n- and water: VLE, Figure 8-2 and Table 8-2 (in Problem 8.D2); selectivity in pervap, Problem 18.D14

calcium acetate: Solubility in water, Figure 17-3A

calcium chloride: Solubility in water, Table 17-1

carbon dioxide: Henry’s Law constants in water, Table 12-1; normal CO₂ % in air, Problem 12.D16; diffusivity in gases: air and water, Table 15-1; diffusivity in liquid water and -liquid ethanol, Table 15-3; permeability, Figure 18-5, Table 18-2, and Example 18-2; -viscosity, Example 18-4; solubility in water, Problem 15.D12

carbon monoxide: Henry’s Law constants in water, Table 12-1; permeability, Figure 17-5

carbon tetrachloride-acetic acid-triethylamine: Equilibrium data, Table 13-A1 (appendix to Chapter 13)

cations: Approximate equilibrium constants, Table 19-5

chlorine: Diffusivity in air, Table 15-21; diffusivity in liquid water, Table 15-3; solubility in water, Example 15-8

chlorinated compounds: Henry’s Law constants and solubilities in water, Table 12-2

chlorobenzene: Diffusivity in bromobenzene, Table 15-3

chloroethane: 1,2-dichloroethane and 1,1,2-trichloroethane relative volatility, α_di–tri = 2.24

chloroform-acetone-benzene: Distillation curves, Figure 8-8

citric acid: Solubility in water, Table 17-1

cobalt chloride: Solubility in water, Table 17-1

copper-sodium ion exchange: Equilibrium, Example 19-4

copper sulphate: Solubility in water, Figure 18-3 and Table 18-1

cost indices: Table 11-1

cost of

condensers: Tables 11-2 and 11-3

materials of construction: Table 11-4

packing: Tables 11-2 and 11-3

reboilers: Tables 11-2 and 11-3

towers: Tables 11-2 and 11-3

trays: Tables 11-2 and 11-3

cresol-phenol relative volatility: α_PC = 1.76

cumene = C₆H₅CH(CH₃)₂ is isopropyl benzene

cumene-toluene relative volatility: α_CT = 0.21

cyclohexane: MW = 84; liquid density, Example 19-2 and Problem 19.D2

cyclohexane-n-heptane: Distillation tray efficiencies, Figure 10-15

decane, n-: MW = 142.28; λ and vapor pressure, Example 8-2

p-dichlorobenzene + p-chloroidobenzene: Liquid-solid equilibrium data, Figure 17-8B

diffusivities

gases, Table 15-1

liquids, Table 15-3

dinitronaphthalene: Adsorption isotherm on silica gel, Table 19-2

dioxane-benzene-water: Distribution coefficient, Problem 13.D10

efficiencies, trays: O’Connell correlation for distillation, Figure 10-14 and Eq. (10-6); O’Connell correlation for absorbers, Figure 12-8 and Eq. (12-36)

equipment costs: Tables 11-2 and 11-3

ethane: MW = 30.07; K values, Figures 2-11 and 2-12 and Table 2-3; liquid density, Problem 2.D21; adsorption isotherm on activated carbon, Figure 19-2A

ethanol: MW = 46; λ, C_P,L, C_P,V, liquid density, and MW, Problem 2.D9; λ, Example 4-1; C_P,L, Problem 4.D20; solubility parameter, paragraph following Eq. (13-1); molar liquid density and vapor pressure, Example 15-1; diffusivity in air, Table 15-1; diffusivity in liquid water, Table 15-3; ϕ_B (solvent interaction parameter) = 1.5; surface tension, Example 16-2; λ, C_P,L, Example 18-10

ethanol-acetone: VLE, Problem 4.D7

ethanol-benzene-water: Residue curves, Figure 8-12

ethanol-ethylene glycol-water: Residue curves, Figure 8-14

ethanol and n-propanol relative volatility: α_E–nP = 2.17

ethanol-water: Activity coefficients, Example 15-9; VLE, Table 2-1 and Figures 2-2 to 2-4; Appendix B of Chapter 2, Eqs. (2.B-1) and (2.B-2); molar liquid densities, Examples 15-5 and 15-9; diffusivity, Table 15-3, Example 15-5, and Table 15-4; liquid viscosity, Example 16-2; vapor Schmidt number, Example 16-2; pervaporation data, Figures 18-15 and 18-17

ethyl benzene-β,β′-Thiodipropionitrile-n-hexane: Distribution coefficient, Table 13-3

ethylene: K values, Figures 2-11 and 2-12 and Table 2-3; adsorption isotherms on activated carbon, Figures 19-2A and 19-2B; adsorption isotherm on zeolite, Figure 19-2B

ethylene dibromide and propylene dibromide relative volatility: α_EP = 1.30

ethylene dichloride-benzene relative volatility: α_B–ED = 1.11

ethylene glycol-ethanol-water: Residue curves, Figure 8-14

fish oil leached from halibut livers with diethyl ether: Equilibrium data, Problem 14.E1

fructose: Solubility in water, Table 17-1; adsorption isotherm on IEX resin in Ca²⁺ form, Table 19-2 and Example 19-5

furfural-MIBK-water: Distribution coefficient, Table 13-3

glucose: Solubility in water, Table 17-1; adsorption isotherm on IEX resin in Ca²⁺ form, Table 19-2 and Example 19-5

glycerol: Diffusivity of water in, Table 15-3

heat transfer coefficients (approximate): Table 11-5

helium: Diffusivity in liquid water, Table 15-3; permeability, Figure 18-5 and Table 18-2

haemoglobin: Diffusivity in liquid water, Table 15-3

heptane, n-: MW = 100.2; K values, Figures 2-11 and 2-12 and Table 2-3; viscosity, Example 10-1 and Problem 10.D2; normal bp = 98.4°C; specific gravity and surface tension, Problem 10.D2; surface tension temperature effects, Problem 10.D5; λ, Example 11-1 and Problem 11.D2; C_P,L, Problem 11.D2 and Example 18-3; liquid density, Example 19-3 and Problem 19.D21

HETP: See packings

hexane, n-: MW = 86.17; K values, Figures 2-11 and 2-12 and Table 2-3; λ, C_P,L, C_P,V, and boiling point, Table 2-5; liquid density, Example 2-4; vapor pressure, Problems 2.D14, 2.D27, and 5.D2; λ, Problem 3.D6 and Example 11-1; C_P,L and C_P,V, Problem 3.D6; viscosity, Example 10-1; liquid specific gravity and surface tension, Example 10-2; latent heat, Problem 11.D2; diffusivity in air, Table 15-1

human serum albumin: Adsorption isotherm on Ca-alginate magnetite bead, Table 19-2

H⁺ ion: Equilibrium values on cation exchange resins, Table 18-4 and Problems 19.D14 and 19.D15

hydrogen: Diffusivity in air, ammonia, methane, and water, Table 15-1; diffusivity in liquid water, Table 15-3; permeability, Figure 18-5 and Table 18-2; adsorption isotherm on activated carbon, Figure 19-2A

hydrogen chloride: MW = 36.46; solubility in water, Problem 12.D8

hydrogen sulfide: Henry’s Law constants in water, Table 12-1

ion exchange resin: Properties, Table 19-4 and Examples 19-5 and 19-8; approximate equilibrium constants, Table 19-5

K⁺ ion: Equilibrium values on cation exchange resins, Table 19-4 and Problems 19.D14 and 19.D15

Lead iodide, PbI₂: Solubility product, Example 17-16

Lennard-Jones potential parameters: Table 15-2

linoleic acid-heptane-methylcellosolve + 10.0% water: Distribution coefficient, Table 13-3

lithium chloride: Solubility in water, Table 17-1

magnesium chloride: Solubility in water, Table 17-1; solubility in methanol-water solutions, Figure 17-23

magnesium sulphate: Solubility in methanol-water solutions, Figure 17-23

manganese chloride: Solubility in water, Table 17-1

manganese nitrate (Mn[NO₃]₂)–water: Liquid-solid equilibrium, Figure 17-7

mercury, Hg: Liquid density = 845.3 lbm/ft³, Example 10-3

methane: K values, Figures 2-11 and 2-12 and Table 2-3; λ, C_P,L, C_P,V, and boiling point Table 2-5; solubility in liquid ammonia, Problem 12.D14; permeability, Figure 18-5, Table 18-2, and Example 18-2; viscosity, Example 18-4; adsorption isotherms on activated carbon, Figures 19-2A and 19-3, Tables 19-2 and 19-3, and Example 19-2; adsorption isotherm on zeolite, Table 19-2

methanol: MW = 32.04; liquid density, Problem 2.D1; λ, C_P,L, and C_P,V, Problem 3.E1; λ, Example 4-2; surface tension, Problem 10.D9; ϕ_B (solvent interaction parameter) = 1.9; diffusivity in liquid water, Table 15-3; vapor pressure, Problem 10.D22

methanol-ethanol relative volatility: α_M–E = 1.69

methanol-isopropanol relative volatility: α_M–iP = 2.26

methanol-methyl butyrate-toluene: Residue curves, Figure 11-11

methanol-n-propanol relative volatility: α_M–nP = 3.58

methanol-water: VLE, Table 2-7 in Problem 2.D1; effect methanol weight fraction on salt solubilities, Figure 17-23

methyl butyrate-methanol-toluene: Residue curves, Figure 11-11

methylcyclohexane-n-heptane-water: Equilibrium data, Table 13-6 (in Problem 13.D18)

methylcyclohexane-toluene-ammonia: Equilibrium data, Figure 13-14

β-methylnaphthalene + β-chloronaphthalene: Liquid-solid equilibrium data, Figure 17-8A

Na⁺ ion: Equilibrium values on cation exchange resins, Table 19-4 and Problem 19.D15

naphthalene: Solubility in carbon dioxide, Figure 14-6; diffusivity in air, Table 15-1; adsorption isotherm on activated alumina, Example 19-2

nickel chloride: Solubility in water, Table 17-1

nitrobenzene: MW = 123.11; solubility in water, Problem 12.D4

nitrogen: Permeability, Figure 18-5 and Table 18-2; adsorption isotherm on zeolite, Table 19-2

nitromethane-water: VLE, Table 8-3 (in Problem 8.E1)

nonane, n-: K values, Figures 2-11 and 2-12 and Table 2-3

octane, n-: MW = 114.22; K values, Figures 2-11 and 2-12 and Table 2-3; liquid density, Example 2-4

octanol: MW = 130.23; vapor pressure, Problems 8.D11 and 9.D19

oil leaching from meal with benzene: Equilibrium data, Table 14-2 and Figure 14-5

oleic acid-heptane-methylcellosolve + 10.0% water: Distribution coefficient, Table 13-3

oxygen: Henry’s law constant in water, Table 15-6; permeability, Figure 18-5 and Table 18-2

packings, random

absorption in water, approximate H_OG: Table 16-3

capacity factor Nutter rings: Figure 10-29

F factor: Table 10-3

flooding: Figure 10-27 and Eq. (10-39a)

HETP (approximate): Paragraph before Eq. (10-37c)

HETP Nutter rings: Figure 10-28

HETP Pall rings: Figure 10-26

HTU estimation: Eqs. (16-37) and (16-38) and Figures 16-5 to 16-7

Alternate HTU estimation: Eq. (16-40) and Table 16-2

pressure drop: Figure 10-27, Eq. (10-39b), and Table 10-3

sizing factor: Eq. (10-38) and Table 10-5

packings, structured

capacity factor Intalox 2T: Figure 10-29

F factor: Table 10-4

HETP (approximate): Eq. (10-37c)

HETP Norton Intalox 2T: Figure 10-28

pentane, iso-: K values, Figures 2-11 and 2-12 and Table 2-3

pentane, n-: MW = 72.15; K values, Figures 2-11 and 2-12 and Table 2-3; λ, C_P,L, C_P,V, and boiling point, Table 2-5; liquid density, Problem 2.D21; vapor pressure, Problems 2.D27 and 5.D2; λ, C_P,L, and C_P,V, Problem 3.D6; diffusivity in air, Table 15-1

pentanol, 2-: Diffusivity in air, Table 15-1

permeability of gases: Figure 18-5 and Table 18-2

phenol-cresol relative volatility: α_PC = 1.76

polarities of compounds: Table 8-1

polymer latex suspensions: Gel formation in UF, x_g ∼50 vol%

polysaccharides: Gel formation in UF, x_g < 1.0 wt%

potassium chloride: Diffusivity in water, Table 15-3; solubility in water, Table 17-1; solubility in methanol-water solutions, Figure 17-23; population density, Eq. (17-34); density = 1998 kg/m³; aqueous solution density, homework Problem 17-D16

potassium chromate: Solubility in water, Figure 17-3A

potassium fluoride: Solubility in water, Table 17-1

potassium nitrate: Solubility in water, Table 17-1

potassium sulphate: Solubility in methanol-water solutions, Figure 17-23

propane: K values, Figures 2-11 and 2-12 and Table 2-3; diffusivity in gaseous n-butane and in 2-butane, Table 15-1; Adsorption isotherm on activated carbon, Figure 19-2A

propanol, iso- (aka 2-propanol): Vapor pressure, Problem 2.D22; diffusivity in air, Table 15-1 and Problem 15.D22; diffusivity in water vapor, Problem 15.D22

propanol, iso, and n-propanol relative volatility: α_iso–n = 1.86

propanol, iso, and water VLE: Table B-1 (in Appendix B)

propanol, n-: Vapor pressure, 6.D4; ϕ_B (solvent interaction parameter) = 1.2; diffusivity in water and of water in, Table 15-3

propylene: K values, Figures 2-11 and 2-12 and Table 2-3

propylene dibromide and ethylene dibromide relative volatility: α_EP = 1.30

pyridine-chlorobenzene-water: Equilibrium data, Table 13-7

sand, dry: Density, Problem 14.D2

seawater: Approximate weight fraction total dissolved salts = 0.035; average density = 1.025 g/cm³

silica gel: Properties as adsorbent, Table 19-1, Example 19-3, and Problems 19.D4 and 19.D6

silver bromide: Solubility constant, K_S,AgBr = 4.1 × 10^–13 (mol/L)² at 18.0°C

silver nitrate: Solubility in water, Table 17-1

sodium acetate: Na₂C₂H₃O2, MW = 82.04; MW hydrate Na₂C₂H₃O2·3H₂O = 136.09; solubility in water, Figure 17-3A and Table 17-1

sodium carbonate: Enthalpy-composition diagram Na₂CO₃–water liquid-solid equilibrium, Figure 17-12; partial pressure aqueous solutions of at 20.0°C, Example 17-7

sodium chloride: MW = 58.45; diffusivity in water, Table 15-3 and Example 18-7; density, Example 15-7; solubility in water, Problem 15.D23, Figure 17-3A, and Table 17-1; eutectic composition and temperature, after Example 17-4; solubility in methanol-water solutions, Figure 17-23; osmotic pressure coefficient, Example 18-4 and Problem 18.D14

sodium chromate: Solubility in water, Figure 17-3A

sodium nitrate: Solubility in water, Table 17-1

sodium sulphate: Solubility in water, Figure 17-3A and Table 17-1; solubility in methanol-water solutions, Figure 17-23

sulfur dioxide: Henry’s law constant in water, Example 16-3

sucrose: MW = 342.3; diffusivity in water and gelatin-water solutions, Table 15-3; solubility in water, Table 17-1; dilute aqueous solution, density and osmotic pressure, Problem 18.D4

sugar: Effective equilibrium constant for leaching from sugar cane into water, Problems 14.D8 and 14.D9

toluene: MW = 92.14; liquid density and viscosity, Example 13-5; interfacial tension with water, Example 13-5; liquid density, C_P,L, and adsorption isotherm on silica gel, Problem 18.D4; Adsorption isotherm on silica gel, Problem 18.D21; adsorption isotherm on -gas-phase activated carbon, Problem 18.D16

toluene-benzene relative volatility: Problem 4.G2

toluene-cumene relative volatility: α_TC = 1/0.21

toluene-methanol-methyl butyrate: Residue curves, Figure 11-11

toluene-xylene relative volatility: α_T–X = 3.03

trays:

capacity factor, Figure 10-29

crest height over weir, Eq. (10-26)

downcomer pressure drop, Eq. (10-27)

dry pressure drop, Eq. (10-24) and Figure 10-23

efficiencies: O’Connell correlation for distillation, Figure 10-14 and Eq. (10-6)

equivalent HETP, Figure 10-28

K_v valve trays, Eq. (10-34b)

O’Connell correlation for absorbers, Figure 12-8 and Eq. (12-36)

orifice coefficient, Eq. (10-25)

Tyler screen sizes: Table 17-2

ultrafiltration solute retention: Figure 18-11

urea: Density of crystals = 1.33 g/ml

washing equilibrium: Eq. (14-1)

water: MW = 18.016; liquid density, Problem 2.D.2; λ, C_P,L, C_P,V, and liquid density, Problem 2.D9; λ, C_P,L, and C_P,V, Problem 3.E1; λ, Example 4-1; λ, C_P,L, and C_P,V, Problem 4.D23; vapor pressure, Problems 8.D10, 8.D15, and 9.D19 and Example 15-11; viscosity, Problem 10.D14a and Example 15-8; surface tension, Problem 10.D15 and Example 16-2; solubility parameter, paragraph following Eq. (13-1); diffusivity of water in air, Table 15-1 and Problems 15.D6, 15.D15, and 15.D22; diffusivity of various solutes in liquid water, Table 15-3; solubility of various solutes in, Figure 17-3 and Table 17-1; ϕ_B (solvent interaction parameter) = 2.26 (2.6 also recommended); λ, C_P,L, Example 18-10

water-benzene-ethanol: Residue curves, Figure 8-12

water and n-butanol: VLE, Figure 8-2 and Table 8-2 (in Problem 8.D2)

water-ethanol: VLE, Table 2-1, Figures 2-2 to 2-4, and Eqs. (2.B-1) and (2.B-2) in Appendix B of Chapter 2; diffusivities, Table 15-4

water-ethanol-ethylene glycol: Residue curves, Figure 8-14

water and iso propanol VLE: Table B-1 (in Appendix B)

water-methanol: VLE, Table 2-7 (in Problem 2.D1)

water-nitromethane: VLE, Table 8-3 (in Problem 8.E1)

xylene: Adsorption isotherms on silica gel, Example 19-3 and Problem 19.D21

xylene, p-: Adsorption isotherms on silica gel, liquid density, and C_P,L, Problem 19.D6

xylene (meta, ortho, para)-β,β′-Thiodipropionitrile-n-hexane: Distribution coefficients, Table 13-3

xylene-toluene relative volatility: α_T–X = 3.03

zeolite molecular sieve: Adsorbent properties, Table 19-1; ethylene adsorption isotherm, Figure 19-2B

Zr(NO₃)₄: Extraction equilibrium data from aqueous solution into TBP-kerosene, Problem 13.D36