- Cover
- Preface
- Chapter 1: TADF Material Design: Photophysical Background and Case Studies Focusing on Cu(I) and Ag(I) Complexesa
- 1.1 Introduction
- 1.2 TADF, Molecular Parameters, and Diversity of Materials
- 1.3 Case Study: TADF of a Cu(I) Complex with Large ΔE(S1–T–T1)
- 1.4 Case Study: TADF of a Cu(I) Complex with Small ΔE(S1–T–T1)
- 1.5 Energy Separation ΔE(S1–T–T1) and S1 → S → S0 Fluorescence Rate
- 1.6 Design Strategies for Highly Efficient Ag(I)‐Based TADF Compounds
- 1.7 Conclusion and Future Perspectives
- Acknowledgments
- References
- Chapter 2: Highly Emissive d10 Metal Complexes as TADF Emitters with Versatile Structures and Photophysical Properties
- 2.1 Introduction
- 2.2 Phosphorescence and TADF Mechanisms [50, 51]
- 2.3 Structure‐Dependent Photophysical Properties of Four‐Coordinate [Cu(N^N)2] Complexes
- 2.4 Flattening Distortion Dynamics of the MLCT Excited State
- 2.5 Green and Blue Emitters: [Cu(N^N)(P^P)] and [Cu(N^N)(P^X)]
- 2.6 Three‐Coordinate Cu(I) Complexes
- 2.7 Dinuclear Cu(I) Complexes
- 2.8 Ag(I), Au(I), Pt(0), and Pd(0) Complexes
- 2.9 Summary
- References
- Chapter 3: Luminescent Dinuclear Copper(I) Complexes with Short Intramolecular Cu–Cu Distances
- 3.1 Introduction
- 3.2 Overview of Luminescent Dinuclear Copper(I) Complexes
- 3.3 Structural and Photophysical Studies of the Dinuclear Copper(I) Complexes: [Cu(µ‐C∧N)]2 (C∧N = 2‐(bis(trimethylsilyl)methyl)pyridine Derivatives) (C∧N = 2‐(
- 3.4 Conclusion
- Acknowledgment
- References
- Chapter 4: Molecular Design and Synthesis of Metal Complexes as Emitters for TADF‐Type OLEDs
- Chapter 5: Ionic [Cu(NN)(PP)]+ TAD9727 F Complexes with Pyridine‐based Diimine Chelating Ligands and Their Use in OLEDs TAD9727 F Complexes with Pyridine‐based Diimine Chelating Ligands and
- Chapter 6: Efficiency Enhancement of Organic Light‐Emitting Diodes Exhibiting Delayed Fluorescence and Nonisotropic Emitter Orientation
- Chapter 7: TADF Kinetics and Data Analysis in Photoluminescence and in Electroluminescence
- Chapter 8: Intersystem Crossing Processes in TADF Emitters
- Chapter 9: The Role of Vibronic Coupling for Intersystem Crossing and Reverse Intersystem Crossing Rates in TADF Molecules
- Chapter 10: Exciplex: Its Nature and Application to OLEDs
- Chapter 11: Thermally Activated Delayed Fluorescence Materials Based on Donor–Acceptor Molecular Systems
- 11.1 Introduction
- 11.2 TADF OLEDs
- 11.3 Basic Considerations in Molecular Design of TADF Molecules
- 11.4 Typical Donor–Acceptor Molecular Systems with High TADF Performance
- 11.5 Organoboron‐based TADF Molecules
- 11.6 TADF Polymers
- 11.7 Intermolecular D–A System for TADF Emission
- 11.8 Summary and Outlook
- References
- Chapter 12: Photophysics of Thermally Activated Delayed Fluorescence
- 12.1 Introduction
- 12.2 Comments on the Techniques Used in Our Studies
- 12.3 Basic Absorption and Emission Properties
- 12.4 Phosphorescence and Triplet State Measurements
- 12.5 Characteristics of the Delayed Fluorescence
- 12.6 Understanding Which Excited States are Involved
- 12.7 Excited‐state Properties
- 12.8 Dynamical Processes
- 12.9 Emitter–host Interactions
- 12.10 Energy Diagram for TADF
- 12.11 Final Comments
- Acknowledgments
- References
- Chapter 13: Thioxanthone (TX) Derivatives and Their Application in Organic Light‐emitting Diodes
- Chapter 14: Solution‐Processed TADF Materials and Devices Based on Organic Emitters
- Chapter 15: Status and Next Steps of TADF Technology: An Industrial Perspective
- Index
- End User License Agreement
Highly Efficient OLEDs
Materials Based on Thermally Activated Delayed Fluorescence
Edited by Hartmut Yersin
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