INDEX

Functionalization of Semiconductor Surfaces, First Edition

Edited by Franklin (Feng) Tao and Steven L. Bernasek.

© 2012 John Wiley & Sons, Inc. Published 2012 by John Wiley & Sons, Inc.

ab initio 32, 233ff, 248, 251, 258, 267, 303

acenaphthylene 163, 175, 176, 189

acetaldehyde 71, 146, 219, 287

acetone 71, 72ff, 139, 196, 219, 220, 278, 287ff, 294, 296

acetophenone 124, 266, 287, 290ff, 295

acetylene 54, 57, 61, 66, 78, 120, 122, 151, 263, 380

adatom 13, 16, 33, 40, 45, 52, 61, 69, 70, 77, 80, 90, 93, 96, 98, 100, 103, 108ff, 112, 115, 120, 124, 134ff, 165, 176, 178ff, 182, 185ff, 189, 194, 203, 211, 217, 271

AES 16ff, 351

AIMD 234, 239, 244, 246, 249, 252, 256, 271

alcohols 111, 218, 228, 306, 327, 339, 342, 345, 355, 359, 372

ALD 348, 353, 359, 389ff

alkene grafting 404, 407

alkylamines 202

amines 111, 113, 198, 190ff, 206, 208, 226, 339, 358, 407

aminobenzene 150

ammonia 193, 197, 198, 358

aniline 207ff, 227

anthracene 163ff

aromatic 27, 89, 92ff, 96, 102, 105ff, 110, 113, 116, 125, 130ff, 137, 143ff, 151, 163ff, 169, 173, 179, 189ff, 206, 209, 215, 227, 324

aromatic amines 207, 209, 211, 227

aromaticity 92, 94ff, 105, 106, 163, 165, 171, 207ff, 210ff,

ARUPS 167

azide 127ff, 151

 

benzene 89ff, 91, 93, 95, 98ff, 105, 112, 114ff, 116ff, 163, 165, 171, 173, 188ff, 207ff, 211, 213, 297, 326, 351, 356

benzonitrile 124, 143

biacetyl 71, 219

bio-FET 411, 419

biological molecules 331, 401, 423

biomolecules 3, 216, 401, 405, 407, 411, 415, 419

biosensors 5, 8, 321, 329, 331, 403, 415, 422, 429

biphenyl 116ff, 138ff

BLYP 238, 248ff

Bohlmann bands 199, 202

butadiene 32, 52, 57, 63ff, 69ff, 91, 112, 249ff, 253ff, 256ff

2-butene 58ff

 

carboxylic acids 220ff, 226, 317, 407

catalysts 2ff, 42ff, 45, 306, 315ff, 320ff

chain reaction 39, 113, 141ff, 144, 278, 280ff, 285ff, 289ff, 292ff, 298, 317ff, 322, 363

chemical sensors 302

Clar's sextet 163ff, 177ff, 180

CMTE 140

conjugated dienes 8, 63, 91, 234, 247, 250, 256, 263, 266

contact angle 305, 312, 327, 354ff, 364, 367

contact patterning 387

corner-hole atom 33

coronene 115, 163ff, 173ff. 189

covalent bonding 5, 44, 116, 149, 179

C-terminated 360ff, 364, 366, 368, 372

CVD 28, 36

cyano 140, 323, 324

cyclic aliphatic amines 198, 202, 203

cycloaddition 31ff, 51ff, 58ff, 58ff, 62, 66ff, 70, 71ff, 74, chap 4, chap 6, chap 8, 252, 254, 258, 260, 263ff, 267ff

[2+2] cycloaddition 32, 51ff, 93, 95ff, 111, 120ff, 132, 175, 204, 207, 211, 219, 221ff, 233, 250, 259, 264ff

[4+2] cycloaddition 32, 51ff, 63, 70ff, 90ff, 95, 101, 112, 115, 120, 129, 133ff, 180, 207, 211ff, 217, 223, 227, 233, 250ff, 257ff, 260, 262, 265, 267ff, 271

cyclocondensation 113, 147ff

cyclohexadiene 54, 61ff, 65, 66ff, 99, 150, 249ff, 258ff, 267ff, 272

cyclopentadiene chap 4, 67ff, 134, 22p

cyclopentene 32, 59ff, 65, 82, 227

 

dangling bond 29, 33ff, 37ff, 43, 45, 52, 62, 71, 90, 94, 99, 108ff, 112, 116, 124, 137ff, 140ff, 148, 165, 179, 180, 183, 185ff, 188ff, 193, 194, 263, 277, 279ff, 283, 287ff, 293, 298, 306, 313, 317, 323, 363, 364, 403, 406, 407

DAS model 13, 14, 16, 18, 33

DFT calculations 53, 58ff, 61ff, 66, 69, 72, 74ff, 77ff, 93, 95, 99, 109, 111ff, 115ff, 118, 120, 122ff, 127ff, 134, 136, 165ff, 169ff, 173, 176ff, 181ff, 194, 196ff, 211ff, 215, 219, 224ff, chap 9, 298, 321

Diamond (100) 8, chap 3

Diels-Alder chap 4, 112, 115, 121, 129, 250ff, 254ff, 258, 260, 264, 268ff

dienes 8, 32, 53, 62ff, 66ff, 71, 82, 91, 112, 234, 247, 250, 256, 263, 266

dimer rows 29, 30, 60, 94, 99, 103, 108, 116, 120, 143, 144, 165, 168ff, 172, 174ff, 189, 205, 216, 263, 266, 278, 285, 287, 289ff

dissociative addition 111, 116, 118, 133

dissociative adsorption 61, 94, 136, 172, 197ff, 201, 203, 205, 208ff, 218ff, 226

DNA 2, 44, 216, 313, chap 13

 

electrochemistry 43, 45, 313, 317, 322, 325

electron transport 143, 299

electronegativity 33, 81, 97, 137, 194ff, 347, 365

electrophilic 31, 32, 71, 77, 90ff, 93, 124, 193, 202, 205, 210, 219, 225, 306

empty state 29, 59, 67, 108, 110, 180, 185, 186, 271, 272

etching 5, 28, 110, 302, 303, 339ff, 347, 350ff, 356, 370, 376

ethylene chap 4, 111ff, 120, 124, 250ff, 263, 357

ethylenediamine 81, 127, 204ff, 226

 

faulted half 90, 178, 179, 184, 185, 186, 188

FET 411, 419, 420

filled state 56, 70, 108, 110, 139, 144, 168, 172ff, 180, 182, 186ff, 214, 216, 219, 224

functional groups 1, 7ff, 27, 33, 44, 80ff, chap 6, 278, 315, 317, 320ff, 327, 363, 387, 407, 409, 415, 429

furan 89ff, 97, 102, 133

Ge (100) 55, 60, 65, 76, 80, 203, 214, 223

grafting 41, 44ff, 146, 305, 307, 318ff, 327, 403, 406ff, 411ff

 

halogen terminated 28, 39ff, 324, 347ff, 351, 355, 359

heteroatom 53, 71ff, 82, 89ff, 93, 95ff, 100ff, 112, 135, 137, 210

heterojunction 145, 295, 359

HOMO 51ff, 90, 194, 196ff

HREELS 16, 18ff, 28, 34, 53ff, 61ff, 69, 71, 74, 76, 78ff, 90, 96, 119, 121, 124, 133ff, 136ff, 173, 209, 212ff, 217, 221, 340, 348, 351ff, 362, 368

H-terminated 34ff, 109, 112, 138ff, 145ff, 266, 277ff, 282ff, 288ff, 296, 302ff, 313ff, 321ff, 339ff, 348ff, 356ff, 362, 370ff, 376, 380, 386, 391, 404, 406ff, 412, 415ff

hydrosylilation 41ff, 145, 305, 314ff, 327, 331, 358, 362ff, 366ff, 381, 386, 409, 410

 

Ion scattering 13ff

IPES 18, 312

IRAS 165ff, 172, 348ff

isocyanate 80ff

isoxazole 90, 95ff, 101, 137

ketone 27, 71, 74, 113, 219, 227, 228, 278, 287

King and Wells 13

Kohn-Sham 235, 237, 30, 257

KS 235, 236, 237, 238, 239, 240, 244, 246, 250, 264, 267, 270

 

LEED 13–15, 28, 30, 53, 61, 221, 304, 313, 314, 331, 340, 341, 362

Lewis acid 43, 149, 193–195, 218, 223, 225, 315, 316, 369

Lewis base 193, 194, 315, 316, 342

LUMO 51, 52

 

mechanical 3, 12, 15, 41–13, 105, 234, 401, 410, 411, 423, 430

MEMS 402

methanol 196, 197, 218, 219, 228, 327, 328, 345, 346, 356, 372, 404

methoxysilane 383

molecular electronics 106, 137, 145, 152, 159, 189, 233, 277, 298, 429, 430

 

nanoparticles 6, 9, 311, 321, 376, 378, 382, 387

nanoscale 2, 5–8, 233, 277, 299, 328, 386 388, 430

nanostructures 2, 38, 39, 233, 277–299, 430

nanowire 402, 422

naphthalene 115, 116, 126, 143, 163–166, 175–179, 181, 184, 189

NEXAFS 20, 24, 53, 60, 63, 64, 66, 79, 80, 119, 124, 133, 172, 183

NH4F 35, 304, 341, 342, 357, 369, 371, 406

NHS 311, 409, 418

nitriles 78, 80

nitrobenzene 126–128, 412

nitrosobenzene 124, 125

nucleophilic 31, 32, 43, 90, 91, 193, 198, 203, 205, 207, 209, 211, 213, 215, 217, 219–221, 223, 226, 251, 253, 254, 268, 306, 317, 319, 322, 324, 353, 357, 358

 

oxazole 90, 95–98, 101, 137

 

PAH 163–165, 168, 170, 172, 174, 176, 178, 180, 182, 184, 186, 188, 189

passivation 149, 150, 302, 303, 345, 356, 370, 371, 378, 430

PBE 237, 248, 257, 264, 267

pentacene 115, 116, 149, 150, 163, 164, 169, 170, 172, 174, 184–189

pericyclic reactions 30, 51, 52, 54, 56, 58, 60, 62, 64, 66, 68, 70, 72, 74, 76, 78, 80, 82–84, 86, 88

perylene 115, 150, 163, 164, 172, 173, 188

phenanthrene 129–131

phenol 118, 119, 228

phenylacetylene 121, 123ff, 149, 295

phosphine 33, 197

phosphonic 403ff, 406

photochemical grafting 318, 323, 407, 411ff

photochemically activated 51, 318–320, 327, 331, 369

photoelectron spectroscopy 16ff, 21, 53, 60, 116, 167, 221, 225, 278, 305, 307, 348, 362, 407

photoluminescence 134, 305, 312

polycyclic aromatic 113, 125, chap 7, 163ff

protecting groups 407

proteins 403, 406ff, 415ff

PTCDA 150, 172

pyrazine 101ff, 134ff, 207, 211, 217, 227

pyridine 96, 100ff, 134ff, 140ff, chap 8, 353ff, 358ff

pyrimidine 101ff, 135ff, chap 8

pyrrole 38, chap 5, 130ff, 207, 209ff, 226, 227

 

radical 38ff, 41ff, 45, 91, 97, 113, 141ff, 181, 210, 260, 262, 277, 280ff, 304, 315ff, 388, 348, 351ff, 407

Raman 20, 311

RBS 351, 356

RCA clean 342

reactivity of halogen terminated 38, 41, 347ff, 351, 355ff, 376

reactivity of H-terminated 36, 37, 41, 304, 339ff, 376

redox 366, 368ff, 378ff

rest atom 16, 33ff, 40ff, 45, 61ff, 69ff, 80, 90ff, 93, 97ff, 108ff, 112, 115ff, 120, 124, 135, 165, 177ff, 194, 203, 211

RHEED 34

sensors 1, 233, 302, 312, 421, 422, 430

SiC(100)-(2×2) 255, 266, 268

SiC(100)-(3×2) 263, 264, 266

silane 42, 302, 305, 367, 378, 380, 382, 403ff, 422

SIMS 310ff, 384ff

spectroscopic ellispsometry 311

sticking coefficient 23, 60ff, 65, 82

styrene 20, 38, 121, 124, 141ff, 266, 278ff, 288, 293ff, 363

 

tautomerism 285

TFAAD 44ff, 407, 409, 412ff

thermally activated 306, 320, 407

thiazole 90, 95ff, 101, 137

thiol 118ff, 285, 310, 314, 325, 339, 376, 383, 385, 387, 401, 408, 409

thiophene 89ff, 100, 102, 133ff, 222ff, 381

tilted dimers 30ff, 61, 82, 194, 263, 266

TPD 22, 53, 55, 63, 66, 71, 78ff, 350ff, 364ff

triazine 134ff, 207, 211

trimethylamine 196ff, 199, 201ff, 225, 227

 

UHV 2, 11ff, 28, 34, 36, 40ff, 122, 278, 301, 308, 347, 358, 365, 367, 376

unfaulted half 90, 178ff, 187ff

UPS 16ff, 53, 55, 62, 69, 80, 116, 136, 167, 278, 296ff, 362, 364

 

van der Waals 4ff, 361

X ray reflectivity 312

XPS 9, 16ff, 21, 60ff, 69, 71, 76, 78, 80, 124ff, 133, 135ff, 147, 150, 185, 201, 208ff, 212ff, 221, 307ff 312, 318, 327, 344, 347ff, 353ff, 406ff, 415, 417, 430

XRD 21

 

zigzag nanostructure 292ff