If we plot EA versus SA graphically, EA needs higher degree of strategy focus and technology breath, as depicted in the following image:

In terms of roles and responsibilities, EA and SA differ in their scope. Basically, the SA scope is limited within a project team and the expected delivery is to make the system quality of the solution for the business. At the same time, the EA scope is beyond SA by identifying or envisioning the future state of an organization.

With the degree of experience, expertise, responsibility, and much more. EA is superior to SA. EA has the vision of end-to-end broader system knowledge; but SA is bound to a specific problem statement. In terms of enterprise role, EA role is pretty close to Chief Architect, whereas SA is at the Senior Architect level.